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Highly stereoselective approaches to .alpha.- and .beta.-C-glycopyranosides

โœ Scribed by Lewis, Michael D.; Cha, Jin Kun; Kishi, Yoshito

Book ID
111942395
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
403 KB
Volume
104
Category
Article
ISSN
0002-7863

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A Highly Stereoselective Synthesis of ฮฑ-Linked C-Glycopyranosides Using 2,2'-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70). -By using V-70 as an effective radical initiator at low temperature, a highly ฮฑ-selective synthesis of C-glycopyranosides (III) is realized. -(KITA, Y.;