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Highly Regioselective Isomerization−Hydroformylation of Internal Olefins to Linear Aldehyde Using Rh Complexes with Tetraphosphorus Ligands

✍ Scribed by Yu, Shichao; Chie, Yu-ming; Guan, Zheng-hui; Zhang, Xumu

Book ID: 126866427
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 103 KB
Volume: 10
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol801247v

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## Abstract A highly regioselective hydroaminomethylation of terminal olefins catalyzed by Rh complexes with 2, 2′, 6, 6′‐tetrakis ((diphenylphosphino)methyl)‐1, 1′‐biphenyl (Tetrabi) ligand has been developed. Up to 99 % amine selectivity, 168 linear/branched amine product ratio (__n/i__), and 97.