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Highly regioselective hydroformylation of 1,5-hexadiene to linear dialdehyde catalyzed by rhodium complexes with tetraphosphorus ligands

✍ Scribed by Shichao Yu; Yu-ming Chie; Xiaowei Zhang; Liyan Dai; Xumu Zhang

Book ID: 108285633
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 192 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.07.066

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## Abstract Rhodium‐catalyzed hydroformylation of 1,5‐hexadiene to dialdehydes was investigated in compressed CO~2~ and in toluene using different fluorinated phosphane compounds as ligands at a temperature of 60 °C. Product yields depend greatly on the ligand used and, of the ligands examined, tri