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Highly Regioselective Isomerization–Hydroaminomethylation of Internal Olefins Catalyzed by Rh Complex with Tetrabi-Type Phosphorus Ligands

✍ Scribed by Liu, Guodu; Huang, Kexuan; Cao, Bonan; Chang, Mingxin; Li, Shengkun; Yu, Shichao; Zhou, Le; Wu, Wenjun; Zhang, Xumu

Book ID
126402355
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
762 KB
Volume
14
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

Highly Regioselective Hydroaminomethylat
Highly Regioselective Hydroaminomethylation of Terminal Olefins to Linear Amines Using Rh Complexes with a Tetrabi Phosphorus Ligand
✍ Guodu Liu; Kexuan Huang; Chaoxian Cai; Bonan Cao; Mingxin Chang; Prof. Wenjun Wu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 208 KB 👁 1 views

## Abstract A highly regioselective hydroaminomethylation of terminal olefins catalyzed by Rh complexes with 2, 2′, 6, 6′‐tetrakis ((diphenylphosphino)methyl)‐1, 1′‐biphenyl (Tetrabi) ligand has been developed. Up to 99 % amine selectivity, 168 linear/branched amine product ratio (__n/i__), and 97.

Highly Regioselective Isomerization–Hydr
Highly Regioselective Isomerization–Hydroformylation of Internal Olefins Catalyzed by Rhodium/Tetraphosphine Complexes
✍ Chaoxian Cai; Shichao Yu; Guodu Liu; Xiaowei Zhang; Xumu Zhang 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 2 views

## Abstract A new class of substituted tetraphosphine ligands has been applied in the rhodium‐catalyzed regioselective isomerization–hydroformylation of internal olefins. The rhodium/tetraphosphine ligand system is highly effective for the isomerization and hydroformylation of 2‐alkenes to form lin