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Highly Regioselective Conversion of Epoxides to β-Hydroxy Nitriles with Cyanide Exchange Resin.

✍ Scribed by B. Tamami; N. Iranpoor; R. Rezaei

Publisher
John Wiley and Sons
Year
2003
Weight
90 KB
Volume
34
Category
Article
ISSN
0931-7597

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Enantioselective Ring Opening of Epoxide
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Enantioselective Ring Opening of Epoxide
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## Abstract Halohydrin dehalogenases (HheA, HheB and HheC) were found to efficiently catalyse a carbon‐carbon bond forming reaction between terminal aliphatic epoxides and cyanide, yielding β‐hydroxy nitriles. With all three enzymes nucleophilic ring opening of epoxides proceeds with high regiosele