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Metalloporphyrins as New Catalysts in the Mild, Efficient and Regioselective Conversion of Epoxides to β-Hydroxy Thiocyanates with NH4SCN.

✍ Scribed by Hashem Sharghi; Alireza Hassani Nejad; Mohammad Ali Nasseri


Publisher
John Wiley and Sons
Year
2005
Weight
168 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The regioselective ring‐opening reactions of some epoxides with ammonium thiocyanate in the presence of a series of new 9__H__‐thioxanthen‐9‐one‐fused azacrown ethers, __i.e.__, **7**–**11** (__Scheme 1__), and also of dibenzo[18]crown‐6 (**12**), __Kryptofix__^®^ __22__ (**13**), and b