Highly Porous Polyhedral Silsesquioxane Polymers. Synthesis and Characterization
β Scribed by Zhang, Chunxin; Babonneau, Florence; Bonhomme, Christian; Laine, Richard M.; Soles, Christopher L.; Hristov, Hristo A.; Yee, Albert F.
- Book ID
- 118745840
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 173 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
A diverse and entirely new class of monomer and polymer technology based on polyhedral oligomeric silsesquioxane (POSS) reagents has been developed. POSS reagents are unique in that they are physically large (approx. 15 A Λdiameter and 1000 amu) and are composed of a robust silicon-oxygen framework
## Abstract Polyhedral oligomeric silsesquioxane (POSS) polymers were synthesized by the dehydrogenative condensation of (HSiO~3/2~)~8~ with water in the presence of diethylhydroxylamine followed by trimethylsilylation. Coating films were prepared by spinβcoating of the coating solution prepared by