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ChemInform Abstract: Polyhedral Oligomeric Silsesquioxane (POSS)-Based Polymers.

✍ Scribed by J. J. SCHWAB; J. D. LICHTENHAN


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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A diverse and entirely new class of monomer and polymer technology based on polyhedral oligomeric silsesquioxane (POSS) reagents has been developed. POSS reagents are unique in that they are physically large (approx. 15 A ˚diameter and 1000 amu) and are composed of a robust silicon-oxygen framework

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## Abstract Polyhedral oligomeric silsesquioxane (POSS) polymers were synthesized by the dehydrogenative condensation of (HSiO~3/2~)~8~ with water in the presence of diethylhydroxylamine followed by trimethylsilylation. Coating films were prepared by spin‐coating of the coating solution prepared by