Highly Fluorous Derivatives of 1,2-Bis(diphenylphosphino)ethane
✍ Scribed by de Wolf, Elwin; Richter, Bodo; Deelman, Berth-Jan; van Koten, Gerard
- Book ID
- 127320108
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 77 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,
In the title compound, [PtI~2~(C~26~H~24~P~2~)]·2CH~2~Cl~2~, the PtI~2~(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] molecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt—I dis