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Highly Fluorinated Weakly Coordinating Monocarborane Anions. 1-H-CB 11 F 11- , 1-CH 3 -CB 11 F 11- , and the Structure of [N( n -Bu) 4 ] 2 [CuCl(CB 11 F 11 )]

✍ Scribed by Ivanov, Sergei V.; Rockwell, Juston J.; Polyakov, Oleg G.; Gaudinski, Christine M.; Anderson, Oren P.; Solntsev, Konstantin A.; Strauss, Steven H.


Book ID
127153865
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
63 KB
Volume
120
Category
Article
ISSN
0002-7863

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[1-Me-1-closo-SnB11H11]βˆ’ as a potential
✍ Eduardo Molinos; Thomas P. H. Player; Gabriele Kociok-KΓΆhn; Giuseppe D. Ruggerio πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 152 KB

## Abstract The __closo__‐stannaborane salt [Rh(PPh~3~)~2~‐(nbd)][1‐Me‐1‐__closo__‐SnB~11~H~11~] reacts with H~2~ in CH~2~ Cl~2~ solution to afford the contact ion‐pair Rh(PPh~3~)~2~(1‐Me‐__closo__‐SnB~11~H~11~), which has been characterized in solution and the solid state by X‐ray diffraction. Β© 2