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Facile Conversion of [(η 6 -C 6 H 6 )Rh(CO) 2 ][1-Et-CB 11 F 11 ] into the Nonclassical Rhodium(I) Carbonyl [Rh(CO) 4 ][1-Et-CB 11 F 11 ]

✍ Scribed by Lupinetti, Anthony J.; Havighurst, Matthew D.; Miller, Susie M.; Anderson, Oren P.; Strauss, Steven H.


Book ID
127234201
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
46 KB
Volume
121
Category
Article
ISSN
0002-7863

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Synthesis and Structure of [Sn4Se11]6–,
✍ Anja Loose; William S. Sheldrick 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 2 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re