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[1-Me-1-closo-SnB11H11]− as a potential weakly coordinating anion: Synthesis of Rh(PPh3)2(1-Me-closo-SnB11H11) and comparisons with Rh(PR3)2 (1-H-closo-CB11 H11)

✍ Scribed by Eduardo Molinos; Thomas P. H. Player; Gabriele Kociok-Köhn; Giuseppe D. Ruggerio; Andrew S. Weller

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
152 KB
Volume
17
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The closo‐stannaborane salt [Rh(PPh~3~)~2~‐(nbd)][1‐Me‐1‐closo‐SnB~11~H~11~] reacts with H~2~ in CH~2~ Cl~2~ solution to afford the contact ion‐pair Rh(PPh~3~)~2~(1‐Me‐closo‐SnB~11~H~11~), which has been characterized in solution and the solid state by X‐ray diffraction. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:174–180, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20218

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