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Assigned cluster 11B and 1H NMR properties of [3-(η6-C6Me6)-closo-3,1,2-RuC2B9H11]

✍ Scribed by Mark Bown; Jaromír Plešek; Karel Baše; Bohumil Štíbr; Xavier L. R. Fontaine; Norman N. Greenwood; John D. Kennedy

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 286 KB
Volume: 27
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260271008

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✦ Synopsis

The cluster "B chemical shifts in members of the important class of closo-3,1,2-metalladicarbaboranes were previously unassigned, and their cluster 'H chemical shifts previously unmeasured. The use of 1' 'B-' 'BJ-COSY and 'H-{"B} NMR spectroscopy to measure and assign the cluster "B and 'H chemical shifts of (previously unreported) [3-(q6-C,Me,)-closo-3,1,2-RuC,B,H, as a model compound is reported. The ' 'B shielding patterns of this species and the nonmetalla simple carbaborane analogue (1,2-C2B,,H,,] are compared and briefly discussed.

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