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Highly enantioselective synthesis of α-methylene-δ-valerolactones by an asymmetric Michael reaction

✍ Scribed by Henryk Krawczyk; Marcin Śliwiński; Jacek Kędzia; Jakub Wojciechowski; Wojciech M. Wolf


Book ID
108284064
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
251 KB
Volume
17
Category
Article
ISSN
0957-4166

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Asymmetric michael reactions : enantiose
✍ François Michelon; Annie Pouilhès; Nguyen Van Bac; Nicole Langlois 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 217 KB

&substituted and a,B-disubstituted 6-0x0 acids are synthetized with high enantiomeric excess from chirnl2-propenyl oxazolines 8 and II. whilst 2-vinyl oxawiines 7 and 10 are less efficient asymmetric inductors.