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Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid

✍ Scribed by Cheng, Dao-Juan; Yan, Liang; Tian, Shi-Kai; Wu, Ming-Yue; Wang, Lu-Xin; Fan, Zi-Li; Zheng, Sheng-Cai; Liu, Xin-Yuan; Tan, Bin

Book ID
121680282
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
485 KB
Volume
53
Category
Article
ISSN
0044-8249

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✍ Takahiko Akiyama; Youichi Saitoh; Hisashi Morita; Kohei Fuchibe 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 83 KB 👁 1 views

## Abstract A novel cyclic dialkyl phosphate was synthesized starting from (+)‐diethyl tartrate. Its catalytic activity as a chiral Brønsted acid has been examined in the Mannich‐type reaction of a ketene silyl acetal with aldimines as a model reaction. The corresponding β‐amino acid esters were ob