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Enantioselective Mannich-Type Reaction Catalyzed by a Chiral Brønsted Acid

✍ Scribed by Takahiko Akiyama; Junji Itoh; Koji Yokota; Kohei Fuchibe

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
101 KB
Volume
116
Category
Article
ISSN
0044-8249

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HBF 4 -catalyzed Mannich-type reaction of silyl enolates with aldimines took place smoothly in aqueous organic solvent to afford b-aminocarbonyl compounds in high yields. The HBF 4 -catalyzed Mannich-type reaction also proceeded smoothly in water without organic solvent in the presence of a surfacta