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Highly Enantioselective Addition of 1,3-Diynes to Aldehydes Catalyzed by a Zinc–Amino Alcohol Complex

✍ Scribed by Bing Zheng; Shuo-Ning Li; Jian-You Mao; Bo Wang; Dr. Qing-Hua Bian; Dr. Shang-Zhong Liu; Dr. Jiang-Chun Zhong; Dr. Hong-Chao Guo; Dr. Min Wang

Book ID: 112020260
Publisher: John Wiley and Sons
Year: 2012
Tongue: English
Weight: 302 KB
Volume: 18
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201200728

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The enantioselective formation of C À C bonds is an area of intense research. [1,2] The asymmetric addition of alkynyl reagents to aldehydes is very useful for the synthesis of chiral secondary propargyl alcohols, which are important building blocks for many chiral organic compounds. [3] Several stu