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ChemInform Abstract: Highly Enantioselective Addition of Trimethylsilylacetylene to Aldehydes Catalyzed by a Zinc—Amino-Alcohol Complex.

✍ Scribed by Zhi-Yuan Li; Min Wang; Qing-Hua Bian; Bing Zheng; Jian-You Mao; Shuo-Ning Li; Shang-Zhong Liu; Ming-An Wang; Jiang-Chun Zhong; Hong-Chao Guo

Publisher
John Wiley and Sons
Year
2011
Weight
40 KB
Volume
42
Category
Article
ISSN
0931-7597

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Highly Enantioselective Addition of Phenylacetylene to Aldehydes Catalyzed by a β-Sulfonamide Alcohol–Titanium Complex
✍ Zhaoqing Xu; Rui Wang; Jiangke Xu; Chao-shan Da; Wen-jin Yan; Chao Chen 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 2 views

The enantioselective formation of C À C bonds is an area of intense research. [1,2] The asymmetric addition of alkynyl reagents to aldehydes is very useful for the synthesis of chiral secondary propargyl alcohols, which are important building blocks for many chiral organic compounds. [3] Several stu