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Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by Novel β-Amino Alcohol—Titanium Complexes.

✍ Scribed by Yan Li; Bin He; Bo Qin; Xiaoming Feng; Guolin Zhang


Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

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The enantioselective formation of C À C bonds is an area of intense research. [1,2] The asymmetric addition of alkynyl reagents to aldehydes is very useful for the synthesis of chiral secondary propargyl alcohols, which are important building blocks for many chiral organic compounds. [3] Several stu