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Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones

โœ Scribed by Zhang, Hui; Yang, Chuan-Bo; Li, Yan-Yun; Donga, Zhen-Rong; Gao, Jing-Xing; Nakamura, Hideaki; Murata, Kunihiko; Ikariya, Takao


Book ID
120843867
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
106 KB
Volume
1
Category
Article
ISSN
1359-7345

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Highly efficient catalysts derived from
โœ Du Xiang-Dong; Dai Li-Xin; Hou Xue-Long; Xia Li-Jun; Tang Ming-Hua ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 207 KB ๐Ÿ‘ 1 views

Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh