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Highly Efficient Chiral Metal Cluster Systems Derived from Ru3(CO)12 and Chiral Diiminodiphosphines for the Asymmetric Transfer Hydrogenation of Ketones.

โœ Scribed by Hui Zhang; Chuan-Bo Yang; Yan-Yun Li; Zhen-Rong Donga; Jing-Xing Gao; Hideaki Nakamura; Kunihiko Murata; Takao Ikariya


Publisher
John Wiley and Sons
Year
2003
Weight
108 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœ Du Xiang-Dong; Dai Li-Xin; Hou Xue-Long; Xia Li-Jun; Tang Ming-Hua ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 207 KB ๐Ÿ‘ 1 views

Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh