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Highly Diastereoselective One-Pot Synthesis of Spiro{cyclopenta[a]indene-2,2′-indene}diones from I-Indanones and Aromatic Aldehydes.

✍ Scribed by Pelayo Camps; Luis R. Domingo; Xavier Formosa; Carles Galdeano; Diana Gonzales; Diego Munoz-Terrero; Silvia Segales; Merce Font-Bardia; Xavier Solans

Book ID
101991157
Publisher
John Wiley and Sons
Year
2006
Weight
32 KB
Volume
37
Category
Article
ISSN
0931-7597

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Silica Nanoparticles as a Highly Efficient Catalyst for the One-Pot Synthesis of 2-Hydroxyacetamide Derivatives from Isocyanides and Electron-Poor Aromatic Aldehydes
✍ Ali Ramazani; Amir Mahyari; Hamed Lashgari; Katarzyna Ślepokura; Tadeusz Lis 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 391 KB 👁 1 views

## Abstract Reaction of an isocyanide with an electron‐poor aromatic aldehyde in the presence of silica nanoparticles (silica NP; __ca.__ 42 nm) proceeds smoothly at room temperature to afford 2‐hydroxyacetamide derivatives in high yields (__Scheme 1__ and __Table 1__).