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Highly Chemoselective and Stereoselective Synthesis of Z -Enol Silanes

✍ Scribed by Herath, Ananda; Montgomery, John

Book ID
126453349
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
100 KB
Volume
130
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Highly regio and stereoselective prepara
Highly regio and stereoselective preparation of Z silyl enol ethers and Z enol esters from ketones via manganese enolates
✍ GΓ©rard Cahiez; Bruno FigadΓ¨re; Patrick ClΓ©ry πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 327 KB

Mn-cnolam are easily and quandtattvciy abtakd under mild mt&io~~ (THF. -1OaC to rt. Ih) by tmument C# ketones with tmmatic Mn-ami&.s such as Ph(Me)NMnZ. They allow to prepare 2 siiyl en01 ethers ami 2 emi esters in hi (kinetic product: 2 99%. ZIE: 9317 to 1001 d h yitlds and with an excdent regio-an