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Highly regio and stereoselective preparation of Z silyl enol ethers and Z enol esters from ketones via manganese enolates

✍ Scribed by Gérard Cahiez; Bruno Figadère; Patrick Cléry

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
327 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

Mn-cnolam are easily and quandtattvciy abtakd under mild mt&io~~ (THF. -1OaC to rt. Ih) by tmument C# ketones with tmmatic Mn-ami&.s such as Ph(Me)NMnZ. They allow to prepare 2 siiyl en01 ethers ami 2 emi esters in hi (kinetic product: 2 99%. ZIE: 9317 to 1001 d h yitlds and with an excdent regio-and stereoselectivity ).

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