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Highly Stereoselective Oxazaborolidinium Ion Catalyzed Synthesis of ( Z )-Silyl Enol Ethers from Alkyl Aryl Ketones and Trimethylsilyldiazomethane

✍ Scribed by Kang, Byung Chul; Shim, Su Yong; Ryu, Do Hyun


Book ID
124049039
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
333 KB
Volume
16
Category
Article
ISSN
1523-7060

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Highly regio and stereoselective prepara
✍ Gérard Cahiez; Bruno Figadère; Patrick Cléry 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 327 KB

Mn-cnolam are easily and quandtattvciy abtakd under mild mt&io~~ (THF. -1OaC to rt. Ih) by tmument C# ketones with tmmatic Mn-ami&.s such as Ph(Me)NMnZ. They allow to prepare 2 siiyl en01 ethers ami 2 emi esters in hi (kinetic product: 2 99%. ZIE: 9317 to 1001 d h yitlds and with an excdent regio-an