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High-resoluttin 29Si NMR in solid silicates: Correlations between shielding tensor and Si-O bond length

✍ Scribed by A.-R. Grimmer; R. Peter; E. Fechner; G. Molgedey

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 371 KB
Volume: 77
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)80158-3

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✦ Synopsis

Zetttralmstztut fhr attorgattrsche C/tetttte der Akadettrte der Wtssetrsciraftetz der DDR, I I99-Brrlur, DDR Reccwed 7-7 August 1980 "SI NhlR spectra of polycrystallmc Ca6 [SI~O,I(OH)~] and [(CH3)4N1 gS1g0x1 69H20 were measured usmg the cross polarlzatmn double-resonance technique Observed shleldmg tensors are related to the l.nown SI-0 bond systems The arrangement of the four St-0 bonds III the S104 tetrahedrn 1s rcfiected by the *'Sx shleldmp tensor TIC most shlcldcd ducctlon corresponds to the shortest Q-0 bond.

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