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Correlation between individual SiO bond lengths and the principal values of the 29Si chemical shift tensor in solid silicates

✍ Scribed by A.-R. Grimmer

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
416 KB
Volume
119
Category
Article
ISSN
0009-2614

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✦ Synopsis

%I sluelding lensor data for sohd silrwres are compared =ilh structural data of the correspondmg SIO, tewahedra. demonstrating a hnear relallonship between mdlvldual SI-0 bond lengths and Ihe "bond dmxrlon related" shieldmg along the directions of the rour Si-0 bonds. This result is interpreted in renns or Ihe kac~ronal s characw_r of the salicon and oxygen hybrid orbit& involved in the 5-O bonds.

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