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Correlation between the isotropic 29Si chemical shifts and the mean silicon-oxygen bond lengths in silicates

✍ Scribed by A.-R. Grimmer; R. Radeglia

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 324 KB
Volume: 106
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80292-4

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✦ Synopsis

Using known N3IR and structural data of solid silicates the linear correlation % = 1.187 X lo4 d(Si-0) -2014 between the isotropic z9Si NMR chemical shifts B (ppm) and the "isotropic" mean bond lengths d(Si-0) (nm) has been established. The results of semi-empirical calculations are in good agreement with this equation.

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