High-resolution transient-double-resonance spectroscopy in SF_6
β Scribed by Larsen, D. M.; Walpole, J. N.; Mooradian, A.; Moulton, P. F.
- Book ID
- 115414615
- Publisher
- Optical Society of America
- Year
- 1977
- Tongue
- English
- Weight
- 468 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0146-9592
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The infrared absorption spectrum of SF6 embedded in large liquid He, clusters was studied in the range around 946.3 cm-' using a cw diode laser. A sharp peak ( fwhm < 300 MHz) accompanied by two weaker satellite bands of larger halfwidth ( = 1 GHz) were recorded for different mean He cluster sizes (
This note reports infmred spectra of SF6 and BC13 in argon matrices at 10 I( and 0.01 cm-' resolution. At this resolution we observe a wealth of structure not observed at the commonly used resolution of 05 cm-l or poorer-Analyses of such specrra will yield important information on the structure and