High resolution ion cyclotron resonance spectroscopy
โ Scribed by Robert T. McIver Jr.; Anthony D. Baranyi
- Book ID
- 107771451
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 827 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0020-7381
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An ion cyclotron resonance (ICR) absorption spectrum has been obtained by exciting an ICR spectral segment with a fixed-frequency electric field pulse, followed by broad-band detection, digitization of the (rime-domain) transient response, and digital Fourier transformation to produce the (frequency
For ion cyclotron resonance, a capacitively coupled open cell variant with fourfold radial symmetry was constructed and tested for axial excitation-ejection of large ions at high resolution. With a reverse of frequency sweep direction, this cell gave substantial improvements in signal-to-noise ratio
This paper reports first use of 2 numeric3I decomalutian procedure for producing ampl'litudecarrccted, phwsecnrrectcd absorption-mode Fourier tmnsform ion cyclotron resonance fIT ICR) spectm. Compared to m;tSnirude-mode TT ICR spectral display, tk RCB metfiod =n enlwxe mass resolution by a factor of