The high-resolution Raman spectrum of the Q, R, and S branches of the ν 5 bending fundamental of SF 6 has been recorded at a temperature of 195 K (dry ice) and a pressure of 39 mbar. This is the first study ever performed of a ν 5 band of an XY 6 molecule. It has been analyzed thanks to the HTDS sof
High-Resolution Spectroscopy and Analysis of the ν4 Bending Region of SF6 near 615 cm−1
✍ Scribed by V. Boudon; G. Pierre; H. Bürger
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 250 KB
- Volume
- 205
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution Fourier transform spectrum of the nu(4) bending region of SF(6) near 615 cm(-1) has been recorded at 213 K. We were able to perform a simultaneous analysis of the nu(4) and nu(4) + nu(6) - nu(6) bands of the main isotopomer, namely (32)SF(6). This is the first detailed analysis of a hot band for this molecule. The nu(4) band of (34)SF(6) was also analyzed and the Q branch of the nu(4) band of (33)SF(6) was identified. In both cases we used the HTDS software developed in Dijon. Copyright 2001 Academic Press.
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