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First High-Resolution Raman Spectrum and Analysis of the ν5 Bending Fundamental of SF6

✍ Scribed by V. Boudon; D. Bermejo

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
336 KB
Volume
213
Category
Article
ISSN
0022-2852

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✦ Synopsis

The high-resolution Raman spectrum of the Q, R, and S branches of the ν 5 bending fundamental of SF 6 has been recorded at a temperature of 195 K (dry ice) and a pressure of 39 mbar. This is the first study ever performed of a ν 5 band of an XY 6 molecule. It has been analyzed thanks to the HTDS software (http://www.u-bourgogne.fr/LPUB/shTDS.html) developed in Dijon. This contribution should be of help in understanding the role hot bands in the strong absorbing ν 3 region.

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