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High pressure mediated Diels-Alder reaction of furan with dialkyl (acetoxymethylene)malonate

✍ Scribed by Sera, Akira; Ohara, Meguru; Kubo, Toshiaki; Itoh, Kuniaki; Yamada, Hiroaki; Mikata, Yuji; Kaneko, Chikara; Katagiri, Nobuya

Book ID
127140509
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
685 KB
Volume
53
Category
Article
ISSN
0022-3263

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The Intramolecular Diels-Alder reactions of furans possessing a 2-alkyl substituent with a terminal @unsaturated ketone have been surveyed. The consequences of varying the degree of substitution of the furan, the bridging chain length, and position of the activating group on the dienophile upon the