Hexacoordinated Group-14 Elements with Phosphorus Donor Ligands: Syntheses and Structures of Me2E[C(PMe2)2(SiMe3)]2 (E = Si, Ge, Sn)
✍ Scribed by Karsch, Hans H. ;Deubelly, Brigitte ;Keller, Ursula ;Bienlein, Fritz ;Richter, Roland ;Bissinger, Peter ;Heckel, Maximilian ;Müller, Gerhard
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1996
- Tongue
- English
- Weight
- 615 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Density functional calculations at the BP86/TZ2P level were carried out to understand the ligand properties of the 16‐valence‐electron(VE) Group 14 complexes [(PMe~3~)~2~Cl~2~M(E)] (1ME) and the 18‐VE Group 14 complexes [(PMe~3~)~2~(CO)~2~M(E)] (2ME; M=Fe, Ru, Os; E=C, Si, Ge, Sn) in co
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.