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Hexacoordinated Group-14 Elements with Phosphorus Donor Ligands: Syntheses and Structures of Cl2E[C(PMe2)2(SiMe3)]2 (E = Si, Ge, Sn)

✍ Scribed by Karsch, Hans H. ;Deubelly, Brigitte ;Keller, Ursula ;Steigelmann, Oliver ;Lachmann, Joachim ;Müller, Gerhard


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
691 KB
Volume
129
Category
Article
ISSN
0009-2940

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Transition-Metal Complexes [(PMe3)2Cl2M(
✍ Pattiyil Parameswaran; Gernot Frenking 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 613 KB

## Abstract Density functional calculations at the BP86/TZ2P level were carried out to understand the ligand properties of the 16‐valence‐electron(VE) Group 14 complexes [(PMe~3~)~2~Cl~2~M(E)] (1ME) and the 18‐VE Group 14 complexes [(PMe~3~)~2~(CO)~2~M(E)] (2ME; M=Fe, Ru, Os; E=C, Si, Ge, Sn) in co