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Transition-Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C–Sn) as Ligands; Part 1: Parent Compounds

✍ Scribed by Pattiyil Parameswaran; Gernot Frenking

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
691 KB
Volume
15
Category
Article
ISSN
0947-6539

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Transition-Metal Complexes [(PMe3)2Cl2M(
Transition-Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C–Sn) as Ligands; Part 2: Complexation with W(CO)5
✍ Pattiyil Parameswaran; Gernot Frenking 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 613 KB

## Abstract Density functional calculations at the BP86/TZ2P level were carried out to understand the ligand properties of the 16‐valence‐electron(VE) Group 14 complexes [(PMe~3~)~2~Cl~2~M(E)] (1ME) and the 18‐VE Group 14 complexes [(PMe~3~)~2~(CO)~2~M(E)] (2ME; M=Fe, Ru, Os; E=C, Si, Ge, Sn) in co