Hexaaquanickel(II) chelidonate monohydrate
✍ Scribed by Yasodha, Vaduganathan ;Govindarajan, Subbaiah ;Manivannan, V. ;Büyükgüngör, O.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 571 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title hydrated molecular salt, Ni(H~2~O)~6~·H~2~O, the Ni cation adopts a slightly distorted octahedral geometry. In the crystal structure, the component species interact by way of O—H...O and weak C—H...O interactions, resulting in a three-dimensional network.
📜 SIMILAR VOLUMES
amine][chelidonato(1.5-)]copper(II) chelidonate(0.5-) monohydrate
In the ionic title compound, [Ni(H 2 O) 6 ](C 8 H 6 NO 5 ) 2 Á5H 2 O, the [Co(H 2 O) 6 ] 2+ cation, (4-nitrophenoxy)acetate anions and water molecules engage in O-HÁ Á ÁO hydrogen bonding, generating a three-dimensional hydrogen-bonded network.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.050 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Ni(H 2 O) 6 ][O 2 P(OCH 3 ) 2 ] 2 , the hexaaquanickel(II) dication (Ni site symmetry 1) and the organic anion interact by way of intermolecular O-HÁ Á ÁO hydrogen bonds.