Hexaaquanickel(II) Bis(hypophosphite).
✍ Scribed by Natalia V. Kuratieva; Marina I. Naumova; Dmitry Yu. Naumov; Nina V. Podberezskaya
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 55 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.050 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Ni(H 2 O) 6 ][O 2 P(OCH 3 ) 2 ] 2 , the hexaaquanickel(II) dication (Ni site symmetry 1) and the organic anion interact by way of intermolecular O-HÁ Á ÁO hydrogen bonds.
In the ionic title compound, [Ni(H 2 O) 6 ](C 8 H 6 NO 5 ) 2 Á5H 2 O, the [Co(H 2 O) 6 ] 2+ cation, (4-nitrophenoxy)acetate anions and water molecules engage in O-HÁ Á ÁO hydrogen bonding, generating a three-dimensional hydrogen-bonded network.
Single-crystal X-ray study T = 293 K Mean '(Ni±O) = 0.002 A Ê R factor = 0.031 wR factor = 0.089 Data-to-parameter ratio = 11.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.