Hexaaquamanganese(II) bis{[ N -(3-methoxy-2-oxidobenzylidene)glycylglycinato]copper(II)} hexahydrate
✍ Scribed by Lei, Long-Wei; Jiang, Yin-Zhi; Zou, Yang
- Book ID
- 120191501
- Publisher
- International Union of Crystallography
- Year
- 2010
- Tongue
- English
- Weight
- 796 KB
- Volume
- 66
- Category
- Article
- ISSN
- 1600-5368
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In the title trinuclear zinc(II) complex, [Zn 3 (C 15 H 11 N 2 O 4 ) 2 -(C 5 H 5 N) 2 ], the central Zn II ion has a distorted square-planar coordination involving two O and two N atoms from two bridging N 0 -(2-hydroxybenzoyl)-2-methoxybenzohydrazide ligands. The coordination around the terminal Zn
In the title complex, [Cu(C 4 H 6 N 2 O 3 )(C 5 H 5 N 5 )(H 2 O)], the Cu II atom is five-coordinated in a square-pyramidal geometry by a tridentate glycylglycinate ligand (glygly), an N atom from an adenine ligand (Hade) and a water molecule in the apical position. The Hade coordination is reinforc
In the binuclear centrosymmetric title compound, [Cu 2 Br 4 (C 6 H 7 NO 2 ) 2 ], two 4-methoxypyridine N-oxide ligands bridge two Cu atoms, conferring a square-planar geometry on Cu. Hydrogen bonds of the C-HÁ Á ÁBr type lead to the formation of a sheet structure.
Single-crystal X-ray study T = 173 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.115 Data-to-parameter ratio = 11.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.