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Bis(μ-4-methoxy­pyridine N-oxide-κ2O:O)bis­[dibromo­copper(II)]

✍ Scribed by Zhang, Shi-Guo ;Li, Wei-Nan ;Shi, Jing-Min

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
108 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the binuclear centrosymmetric title compound, [Cu 2 Br 4 (C 6 H 7 NO 2 ) 2 ], two 4-methoxypyridine N-oxide ligands bridge two Cu atoms, conferring a square-planar geometry on Cu. Hydrogen bonds of the C-HÁ Á ÁBr type lead to the formation of a sheet structure.

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Bis(μ-4-sulfobenzoato-κ2O:O′)­bis­[aqua(
Bis(μ-4-sulfobenzoato-κ2O:O′)­bis­[aqua(2,2′-bi­pyridine-κ2N,N′)copper(II)]
✍ Fan, Sai-Rong ;Xiao, Hong-Ping ;Zhang, Li-Ping ;Zhu, Long-Guan 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.