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Hexaaqua­magnesium(II) 2-methyl-5-nitro­benzene­sulfonate dihydrate

✍ Scribed by Xie, Yong-Rong ;Ge, Gen-Wu ;Yuan, Xiao-Yong ;Wan, Dong-Bei ;Yang, Rui-Qing

Book ID
104489909
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
398 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, Mg(H~2~O)~6~~2~·2H~2~O, the Mg^II^ cation lies on an inversion center and is octahedrally coordinated by six water molecules. The 2-methyl-5-nitrobenzenesulfonate anions do not coordinate to the magnesium, but act as counter-anions. The crystal structure is composed of alternating layers of [Mg(H~2~O)~6~]^2+^ cations and anions. The [Mg(H~2~O)~6~]^2+^ cations, water molecules and anions are connected through a complex pattern of hydrogen-bonding interactions, resulting in a three-dimensional supramolecular network.

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