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Diaquabis{2-[(5-méthylpyrazol-3-yl)méthyl]benzimidazole}nickel(II) dichloride dihydrate

✍ Scribed by Sbai, F. ;Chkirate, K. ;Regragui, R. ;Essassi, E. M. ;Pierrot, M.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
502 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.035 wR factor = 0.116 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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2-Méthyl-3-(3-méthyl-1H-pyrazol-5-yl)pyr
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.040 wR factor = 0.112 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Synthèse et mise en évidence par spectro
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New aza heterocycles with benzimidazole, pyrazole and pyridine moieties in the same molecule have been prepared. Preliminary complexing properties with divalent copper salts were determined by means of mass spectrometry (FAB) and a very interesting oxydation reaction with molecular oxygen was shown.