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Hexa-Coordinated bis -Triphenylphosphine Carbonyl Ruthenium(II) Complexes Containing Bidentate Chelating Ligands

✍ Scribed by Joseph, K.; Gopinathan, Sarada; Gopinathan, C.


Book ID
120009138
Publisher
Taylor and Francis Group
Year
1984
Tongue
English
Weight
264 KB
Volume
14
Category
Article
ISSN
0094-5714

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Six-Coordinate Ruthenium(II) Complexes C
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The bis(Ξ· 3 -2-methallyl)ruthenium (II) 1) and the unsymmetrical 1,2-bis-(phosphanyl)ethanes Ph 2 PCH 2 CH 2 PR 2 . The As,P analogue [Ru(Ξ· 3 -2-MeC 3 H 4 ) 2 (ΞΊ 2 -Ph 2 PCH 2 CH 2 AstBu 2 )] (4) was obtained by the same route. The reaction of 2 with hexafluoroacetylacetone afforded the chelate comp