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Heteropoly Acid as a Novel Efficient Catalyst for Fries Rearrangement.

✍ Scribed by Elena F. Kozhevnikova; Eric G. Derouane; Ivan V. Kozhevnikov

Book ID
101936663
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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Aryl arenesulfinates rearrange to the corresponding arenesulfinyl phenols via a thia-Fries rearrangement on catalysis by anhydrous FeCl 3 in dry dichloromethane at room temperature in good to excellent yields.