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FeCl3 as an efficient and new catalyst for the thia-Fries rearrangement of aryl sulfinates

✍ Scribed by Firouz Matloubi Moghaddam; Mohammad G Dekamin; Mohammad Ghaffarzadeh

Book ID: 104231783
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 55 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01735-x

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✦ Synopsis

Aryl arenesulfinates rearrange to the corresponding arenesulfinyl phenols via a thia-Fries rearrangement on catalysis by anhydrous FeCl 3 in dry dichloromethane at room temperature in good to excellent yields.

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