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Methanesulfonic acid/phosphorus oxychloride (MAPO) as a new efficient reagent in the Fries rearrangement

✍ Scribed by Babak Kaboudin


Book ID
104209651
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
440 KB
Volume
55
Category
Article
ISSN
0040-4020

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Graphite/Methanesulfonic Acid (GMA) as a
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## Abstract A new facile method for direct sulfonylation of phenols was developed. Graphite in methanesulfonic acid (GMA) was used to prepare sulfonylphenols by sulfonylation of phenol and naphthalene derivatives with __p__‐toluenesulfonic acid (=4‐methylbenzenesulfonic acid) (__Tableβ€…1__) and the