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Heterodinuclear group 6 metallacarboranes: synthesis and characterization of closo-3,3,3-(CO)3-3-SnPh3-3,1,2-MC2B9H11]− (M = Cr, Mo, W)

✍ Scribed by Jinkwon Kim; Youngkyu Do; Youn Soo Sohn; Carolyn B. Knobler; M. Frederick Hawthrone


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
313 KB
Volume
418
Category
Article
ISSN
0022-328X

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Assigned cluster 11B and 1H NMR properti
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The cluster "B chemical shifts in members of the important class of closo-3,1,2-metalladicarbaboranes were previously unassigned, and their cluster 'H chemical shifts previously unmeasured. The use of 1' 'B-' 'BJ-COSY and 'H-{"B} NMR spectroscopy to measure and assign the cluster "B and 'H chemical