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The relationship between the molecular structure of [3,3-(PMe2Ph)2-closo-3,1,2-PtC2B9H11] and the mechanism of the fluxional behaviour of M(PR3)2-units in closo-twelve-atom metallaheteroboranes

✍ Scribed by Donnacha O'Connell; Trevor R. Spalding; George Ferguson; John F. Gallagher; John D. Kennedy


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
372 KB
Volume
503
Category
Article
ISSN
0022-328X

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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115Β±130 Β°C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 Β΄x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6Β± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4Β± species. Similar re