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Heavy—heavy—light limit and exchanged-atom isotopic effects in atom—diatom reactivity

✍ Scribed by Antonio Laganà; Antonio Aguilar; Xavier Gimenez; Jose' M. Lucas

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
524 KB
Volume
189
Category
Article
ISSN
0009-2614

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✦ Synopsis

The validity of arbitrarily increasing the mass of the exchanged atom when calculating reduced-dimensionality three-dimensional quantum cross sections for heavy-heavy-light reactions has been investigated by considering, as a case study, the Li + FH+LiF+ H system. This exchanged-atom isotopic effect was found to have opposite sign at large and small collision angles, resulting in a partial error compensation for reactions having a bent transition state.

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