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Volume of concert and heavy atom effects in Diels-Alder reaction mechanisms

✍ Scribed by Raymond A. Firestone


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
511 KB
Volume
52
Category
Article
ISSN
0040-4020

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Kinetic effect of pressure on Michael an
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The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent